Which of these represents the best Lewis structure for acetylene (C 2 H 2 )?
A. H-C-C-H (triple bond between C's)
Although carbon dioxide is the primary compound discussed with respect to global warming; of the common atmospheric components the global warming potential (GWP) of a carbon dioxide molecule is very low. Which statement best explains this pair of facts?
C. CO 2 exists in relatively high concentrations.
How many atoms are present in 0.375 mol of palladium (Pd) atoms?
C. 2.26 × 10^23
The greenhouse effect refers to the process by which
C. atmospheric gases trap and return infrared radiation radiated by Earth.
Octane (C 8 H 18 ) is one of the principal components of gasoline. How many moles of CO 2 are produced during the combustion of 3.0 mol of octane? Unbalanced equation: C 8 H 18 + O 2 → CO 2 + H 2 O
C. 24
The top graph shows the mean temperature over the past 160,000 years as determined from ice-core data. Which of graphs A through D best represents the carbon dioxide concentration in air over the same time period as measured from air bubbles trapped in the ice cores?
C. Graph C
Hydrogen gas (H 2 ) is a promising alternative to fossil fuels. How many molecules are present in 1.0 kg of hydrogen gas?
C. 3.0 × 10 26
What is the effect of infrared energy on matter?
D. It increases the vibration of chemical bonds.
Which occurrences or processes are expected to reduce the level of atmospheric carbon? I. Decaying plant and animal remains II. The growth of trees III. Formation of carbonate rock in the ocean IV. Animal respiration
B. II and III only
Although coal is a complex mixture of substances, its elemental composition can be approximated by the formula C 135 H 96 O 9 NS. Using this formula, predict the amount of CO 2 released from the combustion of 1.00 × 10 6 metric tons of coal (about the annual average for a coal-fired power plant). 1 metric ton = 1 × 10 3 kg
B. 3.11 × 10 9 kg
The most abundant greenhouse gas in Earth's atmosphere is:
B. H 2 O vapor
Identify the single most effective strategy to reduce carbon dioxide emissions.
B. Develop alternate energy sources that do not rely on fossil fuels.
Tropospheric ozone (O 3 ) is a greenhouse gas. Why is O 3 not assigned a Global Warming Potential (GWP)?
D. Ozone has a relatively short lifetime in the troposphere and its distribution is not uniform around the world.
Where is most of the carbon on earth stored?
A. in the form of fossil fuels and carbonate minerals and rocks
Which substances are regulated by the Kyoto Protocol? I. argon II. carbon dioxide III. nitrogen IV. nitrous oxide V. sulfur hexafluoride
C. II, IV, and V only
Land use changes have a big impact on global warming because of their effect on albedo. Albedo
C. is the ratio of electromagnetic radiation reflected by a surface to the amount of radiation hitting that surface.
In order to make useful predictions, which factors must be accounted for by climatic models? I. Aerosol Emissions II. Land Use III. Solar Irradiance
D. I, II, and III only
Which of the following has the lowest albedo?
A. Ocean
The heat of combustion of methane, CH 4 , is 50.1 kJ/g. How much heat would be generated if 1.00 mol of methane undergoes complete combustion?
D. 804 kJ
The energy that flows from a warmer body to a colder body is called
A. heat.
The first law of thermodynamics states that
D. energy is neither created nor destroyed.
The measure of how much energy is dispersed in a given process is called the
A. entropy.
In which example is the entropy of the initial state lower than the entropy of the final state?
A. A pot of water boils to produce water vapor at 100°C.
The following molecules contain only single bonds. NH 3 (g) + 3F 2 (g) → NF 3 (g) + 3 HF(g) The bond energies are: N H 391 kJ/mol; F F 158 kJ/mol; N F 272 kJ/mol; H F 566 kJ/mol. Which is the heat evolved or absorbed per mole of NH 3 that reacts with F 2 ?
D. -867 kJ/mol
Which is not a known advantage of natural gas over other fossil fuels?
C. It is far more abundant than any other fossil fuel.
During petroleum refining, catalysts play an extremely important role during the
A. cracking and reforming processes.
The diagram below shows a simplified version of a fractionating column used in the petroleum industry. The compounds that are obtained at position D (bottom)
A. asphalt.
Consider these three compounds. Which are isomers?
B. I and III only
A gasoline's octane rating is a measure of the
A. gasoline's resistance to causing knocking in a vehicle's engine.
A gasoline's octane rating is determined by
A. comparing its burning properties to those of pure isooctane, which has an octane rating of 100.
Oxygenated gasolines are blends of petroleum-derived compounds with oxygen-containing compounds. Which of the following oxygenated compounds has been discontinued in some states because of potential health risks?
C. MTBE
Over the very long run, the energy source that has the greatest potential to meet humanity's needs is
D. solar (the sun).
Assume that an extremely inefficient electrical utility company delivers electrical energy to your home from a natural gas-burning power plant with an overall efficiency of only 31% and your furnace is 85% efficient in converting electrical energy into heat energy. What mass of natural gas the power plant must burn if heating your home requires 3.5 × 10 7 kJ? The heat of combustion of natural gas is 50.1 kJ/g.
A. 2650 kg
Calculate the amount of energy that is saved by replacing a 75-watt incandescent light bulb with an 18-watt fluorescent bulb during the 1500-hour life of the incandescent bulb. One watt is the equivalent of one joule of energy used per second.
A. 308,000 kJ
Power plants generate electricity by harnessing the energy stored in chemical bonds. Which lists, in the correct order, the forms that the energy takes to get from a fossil fuel to an electrical outlet?
D. potential energy → heat energy → electrical energy → mechanical energy
Which of the following has the highest boiling point?
B. Octane
scientists believe they know the average global temperature over the last 160,000 years. Which property of the ice core samples from Antartica provides this information?
C. the 1H/2H ratio
which of the atmospheric components does not contribute to global warming?
C. N2
Neither N2 or O2 are greenhouse gases because
B. their overall electric charge distribution does not change when they vibrate
what international agreement attempted to reduce greenhouse gas emissions?
A. Kyoto Protocol
Find the molar mass of ethano, C2H6O
c. 46.07 g/mol
how many atoms are present in 0.375 mol of palladium (Pd) atoms?
c. 2.26 x 10^23
scientists have correlated average global temperature with atmospheric carbon dioxide levels for the last 160,000 years using ice cores from Antartica. How is carbon dioxide level determined?
a. by measuring the CO2 concentration in trapped air bubbles in the ice layers
which practices might be described as carbon sequestration? I. planting trees II. deforestation III. pumping carbon dioxide deep into the ocean
d. I and III
what is the coefficient for oxygen in the balanced chemical equation for the combustion of heptane (C7H16) unbalanced equation = C2H16 + O2 → CO2 + H2O
a. 11
which country has the highest per capita emission of carbon dioxide
a. US
the history of average global temperature for the last 160,000 years is derived from isotopic analysis of ice layers in Antartica, Scientists study the ____ ratio in____
b. 1H/2H, H20
argon, which compromises almost 1% of the atmosphere, is approximately 27 times more abundant than CO2, but does not contribute to global warming. Which explanation accounts for this fact?
a. single atoms do not have bonds, therefore do not vibrate
calculate the percentage by mass of flourine in sulfur hexaflouride (SF6), a potent greenhouse gas
c. 78%
the industrial revolution is a key point in the earth's atmospheric history because
a. prior to that time large deposits of petroleum and coal were not being used as energy sources
calculate the percent of chlorine in CCl3F (Freon-11)
a. 77.5%
identify the single most effective strategy to reduce carbon dioxide emissions
d. develop alternate energy sources that do no rely on fossil fuels
the heat combustion of ethane, C2H6, is 1560 kJ,mol, what is heat of combustion of ethane in kJ per gram
a. 51.9 kJ/g
the energy that flows from a warmer body to a colder body is called
a. heat
the energy stored in the chemical bonds of fossil fuels is a form of ____ energy
c. potential
the energy of motion is called ____ energy
d. kinetic
the first law of thermodynamics states that
d. energy is neither created or destroyed
based on this reaction and its energy profile CH4 (g) + 2O2 (g) → CO2 (g) + 2H2O (g)
a. exothermic
how is heat energy used to generate electricity
b. heat boils water to make steam, which drives a turbine
which is correct statement of the second law of thermodynamics
a. entropy of the universe is constantly increasing
combustion is a chemical process in which a fuel combines with ____ to release energy and form products
b. oxygen
consider the following equation that describes the complete combustion of propane, C3H8, the bond energies are C-H 416 kJ/mol; C-C 356 kJ/mol; O--O 498 kJ/mol; C--O 803 kJ/mol; H-O 467 kJ/mol. which is the total amount of energy required to break all of the bonds in propane
c. 4040 kJ/mol
which factor did not play a major role in the formation of fossil fuels from plant matter a. high temperature b. high pressure c. an absence of CO2 d. an abundance of sunlight
d. an abundance of sunlight
in the petroleum industry, what does a refinery do
a. it separates crude oil into fractions consisting of compounds with similar boiling points
which is produced in the greatest amount from a barrel of petroleum
b. gasoline
which of the following is not a "clean coal" technology already in use?
d. sequestration, to capture and store CO2 before it is emitted into the atmosphere (gasification, coal washing, and wet scrubbing all are)
why is the mileage a vehicle gets less when burning E85 than 100% gasoline?
c. ethanol has a lower heat of combustion