Organic Chemistry Klein Chapter 9 Alkenes Addition

Are addition reactions exothermic or endothermic?

Are elimination reactions exothermic or endothermic?

Reactions that proceed with a regiochemical preference are said to be...

?

Does a peroxide cause Markovnikov or anti-Markovnikov?

Can there be a carbocation arrangement with hydrohalogenation?

What is the rate-determining step of a hydrohalogenation--proton transfer or nucleophilic attack?

Products of hydrohalogenation where chirality is present tend to be... what kind of mixtures?

Does acid-catalyzed hydration proceed via Markovnikov or anti-Markovnikov?

Do more alkyl substituents branching off a side of a double bond increase the rate of an acid-catalyzed hydration reaction?

What is used for the initial proton transfer in acid catalyzed hydration..

. hydronium ion or water?

What is used as nucleophile to attack carbocation during acid catalyzed hydration... hydronium ion or water?

What functions to deprotonate the oxonium ion during acid catalyzed hydration.

.. hydronium ion or water?

Does increasing the dilution of an acid movie the equilibrium toward producing alcohol during acid-catalyzed hydration?

Products of acid-catalyzed hydration where chirality is present tend to be... what kind of mixtures?

What results from acid-catalyzed hydration?

What are the reagents for oxymercuration-demercuration? (In addition to a nucleophile such as water)

Is there carbocation rearrangement with oxymercuration-demercuration?

Does oxymercuration-demercuration proceed via Markovnikov or anti-Markovnikov?

Is oxymercuration-demercuration syn or anti?

What are reagents for hydroboration-oxidation?

Is hydroboration-oxidation Markovnikov or anti-Markovnikov?

What kind of product does hydroboration-oxidation create?

Is hydroboration-oxidation syn or anti?

Does the -OH in hydroboration-oxidation go to most-substituted or least-substituted?

Is metal a reagent in catalytic hydrogenation?

Is H2O a reagent in catalytic hydrogenation?

Is H2 a reagent in catalytic hydrogenation?

Is catalytic hydrogenation syn or anti?

When the alkene is symmetrical, during catalytic hydrogenation you must watch out for.

.. this type of compound?

Metal is what type of catalyst..

. heterogeneous or homogeneous?

Wilkinson's catalyst is what type of catalyst...

heterogeneous or homogeneous?

Which halogens work with halogenation (full names, alphabetical)?

Is halogenation anti or syn?

What is the reagent for halogenation (in addition to halogen itself, abbreviation)

Can the configuration of the starting alkene (cis/trans) determine the configuration of the product for halogenation reactions?

Is halogenation syn?

What is the reagent for halohydrin formation? (in addition to the halogen)

Does OH end up at more-substituted or less-substituted in halohydrin formation?

Is halohydrin formation anti or syn?

How many -OH groups result from dihydroxylation?

What are the reagents for performing anti dihydroxylation?

What is a common RCO3H used to create an epoxide during anti dihydroxlyation?

What kind of ring is created on an epoxide? (It's a three-membered, cyclic _____.)

What are the most common reagents for syn dihydroxylation?

In oxidative cleavage, each C=C double bond becomes how many C=O bonds?

What is the most common reagent for oxidative cleavage?

A peroxide is used in oxidative cleavage for ...

reductive workup? or oxidative workup?

DMS is used in oxidative cleavage for ... reductive workup? or oxidative workup?